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Phone: 631-242-4249 | Toll-Free: 888-686-3454
The chemical oxygen demand (COD) is one of the most important parameters for the assessment of industrial and municipal wastewater. As a cumulative parameter, COD determines all chemically oxidizable components present in water. Hence, this includes not only biodegradable substances (as in the BOD5), but also chemical compounds that cannot be determined by biological oxidation (e.g. nitrogen compounds such as nitrites). It has also the advantage of a faster availability compared to BOD. The COD indicates the contamination of a water sample. It is therefore also used as an evaluation parameter to determine pollution units in discharges under the German Wastewater Charges Act. By definition (ISO 15705), the COD is the concentration of oxygen that is equivalent to the mass of potassium dichromate that is consumed in total oxidation of organic substances present in the water sample. Mercury sulfate and silver sulfate as well as sulfuric acid are listed as auxiliary reagents.
The COD covers all oxidizable contents of the sample.
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COD is not a quantity-based size but an effect parameter (a requirement), as is illustrated in the following example:
In acid medium, potassium dichromate forms reactive oxygen species, by the reaction with hydrogen ions.
These oxygen compounds are able to oxidize organic compounds such as ethanol or methanol to carbon dioxide.
The consumption of oxidizing agent is independent of the size of the molecule. For example, the oxidation of methanol consumes less oxidant than that of the smaller methane, since less oxygen is consumed in the reaction to carbon dioxide and water. This results in a larger theoretical COD for methane than for methanol. The COD content can be determined from the consumption of potassium dichromate. The evaluation is done photometrically or by titration. Depending on the measurement range, the decrease in concentration of the yellow potassium dichromate or the increase in concentration of the green chromium(III) ion is determined. For all tests with a low measurement range, up to the test NANOCOLOR COD 300 (REF 985033), the former applies. From the test NANOCOLOR COD 600 (REF 985030) on, the increase of the green chromium(III) is determined. An important process in COD determination is decomposition. In analogy to DIN 38409- H41, decomposition is carried out for two hours at 148 °C. A faster decomposition at 160 °C for 30 minutes is also possible. However, this rapid decomposition is not suitable for all tests. Please refer to the instruction leaflet of the respective test. COD decomposition in a microwave oven, in analogy to decompositions with NANOCOLOR NanOx N and NANOCOLOR NanOx Metal, is not permitted for safety reasons.
K2Cr2O7 = potassium dichromate
H+ = hydrogen ion
Cr3+ = Cr(III) ion
K+ = potassium ion
<O> = oxygen compounds
H2O = water
Advantages of the NANOCOLOR analysis system compared to DIN 38 409 H41:
The sample should be thoroughly mixed or homogenized in a blender to be as representative as possible for the COD of the water to be examined.
COD determinations should be performed as soon as possible after sampling. If this is not possible, the pH should be reduced to 2 or less by the addition of 2 mL of concentrated sulfuric acid H2SO4 per 1 L of sample.
Storage of the acidified sample at room temperature: Analysis within 7 days.
Storage of the acidified sample at 4 °C: Analysis within 28 days.
